Durability Performance of Corn Cob Ash–Coconut Shell Ash Concrete Exposed to Simulated Oil Refinery Wastewater
Published 2025-08-26
Keywords
- Corn cob ash,
- Coconut shell ash,
- Durability performance,
- Acid and sulfate resistance,
- Industrial wastewater
- Pozzolanic materials,
- Oil and gas infrastructure ...More
How to Cite
Copyright (c) 2025

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
The durability of concrete in chemically aggressive environments, such as oil refinery wastewater systems, remains a critical challenge in infrastructure development. This study investigates the performance of concrete modified with binary agro-industrial pozzolans—corn cob ash (CCA) and coconut shell ash (CSA)—as partial replacements for ordinary Portland cement (OPC). Six concrete mixes were prepared with 0–30% combined SCMs by weight of binder. The specimens were exposed to 2% sulfuric acid (H?SO?) and 5% sodium sulfate (Na?SO?) for up to 90 days. Key parameters evaluated include compressive strength, mass loss, water absorption, sorptivity, density, and visual deterioration. The results revealed that the 15% replacement mix (M2) achieved optimal performance. It retained more than 94% of the control’s compressive strength at 90 days and recorded the lowest mass loss and permeability under both acid and sulfate attack. SCM addition contributed to secondary pozzolanic reactions, microstructural densification, and reduction in capillary porosity. Visual inspections corroborated quantitative findings, with M2 maintaining sound surface integrity, whereas higher SCM levels (?25%) showed signs of softening and erosion. Although density declined with higher SCM content, the values remained within acceptable structural thresholds. Overall, the findings affirm the suitability of CCA–CSA binary blends for enhancing concrete durability in aggressive industrial environments. The use of these locally sourced pozzolans also promotes sustainable construction and circular economy practices, making the approach particularly beneficial for developing regions and petrochemical infrastructure.
Metrics
References
- A. R. Suleiman, A. M. Soliman, and M. L. Nehdi, "Effect of surface treatment on durability of concrete exposed to physical sulfate attack," Construction and Building Materials, vol. 73, pp. 674–681, 2014. doi: 10.1016/j.conbuildmat.2014.10.006.
- M. F. Najjar, M. L. Nehdi, A. M. Soliman, and T. M. Azabi, "Damage mechanisms of two-stage concrete exposed to chemical and physical sulfate attack," Construction and Building Materials, vol. 137, pp. 141–152, 2017.
- B. K. Moghadas, H. F. Fard, and M. Ghasemi, "Analyzing and reusing industrial wastewater sludge in cement production: Environmental and economic implications," Results in Chemistry, 102299, 2025.
- B. C. Olaiya, M. M. Lawan, K. A. Olonade, and O. O. Segun, "An overview of the use and process for enhancing the pozzolanic performance of industrial and agricultural wastes in concrete," Discover Applied Sciences, vol. 7, no. 3, p. 164, 2025.
- I. C. Attah, R. K. Etim, and J. E. Sani, "Response of oyster shell ash blended cement concrete in sulphuric acid environment," Civil and Environmental Research, vol. 11, no. 4, pp. 62–74, 2019.
- M. F. I. Akhshah, S. N. S. H. N. Azam, and A. Rahim, "Delayed ettringite formation in the marine environment and its relationship to sulphate attack," AIP Conference Proceedings, vol. 2719, no. 1, AIP Publishing, May 2023.
- M. Duque-Acevedo, I. Lancellotti, F. Andreola, L. Barbieri, L. J. Belmonte-Ureña, and F. Camacho-Ferre, "Management of agricultural waste biomass as raw material for the construction sector: An analysis of sustainable and circular alternatives," Environmental Sciences Europe, vol. 34, no. 1, p. 70, 2022.
- S. Jalasideen, "Effect of composite corn cob ash and metakaolin on the durability properties of concrete exposed to chemically aggressive environment," International Journal of Advances in Engineering and Management (IJAEM), vol. 6, no. 08, pp. 645–664, 2024.
- M. U. Hossain, R. Cai, S. T. Ng, D. Xuan, and H. Ye, "Sustainable natural pozzolana concrete–A comparative study on its environmental performance against concretes with other industrial by-products," Construction and Building Materials, vol. 270, p. 121429, 2021.
- P. Murthi, K. Poongodi, and R. Gobinath, "Effects of corn cob ash as mineral admixture on mechanical and durability properties of concrete–A review," IOP Conference Series: Materials Science and Engineering, vol. 1006, no. 1, p. 012027, Dec. 2020.
- E. N. Ogork and A. M. Auwal, "Durability Characteristics of Self-Compacting Concrete Incorporating Corn Cob Ash," CARD International Journal of Engineering and Emerging Scientific Discovery, vol. 2, no. 1, pp. 29–41, 2017.
- K. S. Ranatunga, E. del Rey Castillo, and C. L. Toma, "Evaluation of the optimal concrete mix design with coconut shell ash as a partial cement replacement," Construction and Building Materials, vol. 401, p. 132978, 2023.
- ASTM International, "ASTM C150/C150M-22: Standard specification for Portland cement," 2022.
- Standards Organisation of Nigeria (SON), "NIS 444-1:2014 – Cement – Part 1: Composition, specifications and conformity criteria for common cements," Abuja, Nigeria, 2014.
- British Standards Institution (BSI), "BS EN 1008:2002 – Mixing water for concrete," London, UK, 2002.
- E. Atikpo, M. C. Nnennaya, and V. S. Aigbodion, "Unveiling improved sulfate resistance of high-performance concrete composites using maize cob ash particles and raffia fibers," Chemistry Africa, vol. 7, no. 10, pp. 5355–5366, 2024.
- M. A. Adajar, J. Galupino, C. Frianeza, J. F. Aguilon, J. B. Sy, and P. A. Tan, "Compressive strength and durability of concrete with coconut shell ash as cement replacement," Geomate Journal, vol. 18, no. 70, pp. 183–190, 2020.
- British Standards Institution (BSI), "BS 882: Specification for aggregates from natural sources for concrete," London, UK, 1992.
- British Standards Institution (BSI), "BS EN 12620: Aggregates for concrete – Specification," London, UK, 2013.
- ASTM International, "ASTM C127-15: Relative density and absorption of coarse aggregate," 2015.
- ASTM International, "ASTM C128-15: Relative density and absorption of fine aggregate," 2015.
- K. Terungwa and M. Emmanuel, "Effect of coconut shell ash on the sulfate resisting capabilities of concrete," International Journal of Advanced Engineering Research and Technology, vol. 6, no. 6, pp. 393–399, 2018.
- G. Trancone, G. Policastro, D. Spasiano, et al., "Treatment of concrete waste using organic acids from fermentation," Chemical Engineering Journal, vol. 505, p. 159536, 2025.
- ASTM International, "ASTM C311/C311M-23: Testing fly ash and natural pozzolans," 2023.
- F. He, X. Wang, C. Zhang, Y. Hou, and Y. Liu, "Corrosion rate of concrete under sulfuric acid," Case Studies in Construction Materials, p. e04696, 2025.
- Q. Wu, Q. Ma, and X. Huang, "Mechanical properties and damage evolution of concrete under sulfate attack," Materials, vol. 14, no. 9, p. 2343, 2021.
- ASTM International, "ASTM C39/C39M-23: Compressive strength of cylindrical concrete specimens," 2023.
- British Standards Institution (BSI), "BS EN 12390-3: Compressive strength of test specimens," London, UK, 2019.
- ASTM International, "ASTM C642-21: Density, absorption, and voids in hardened concrete," 2021.
- ASTM International, "ASTM C1585-20: Water absorption of hydraulic-cement concretes," 2020.
- British Standards Institution (BSI), "BS 1881-114: Density of hardened concrete," London, UK, 1983.
- ASTM International, "ASTM C143/C143M-20: Slump of hydraulic-cement concrete," 2020.
- A. S. Sabo Baba, et al., "Application of response surface methodology in predicting and optimizing properties of concrete containing ground scoria and metakaolin blended cement," Journal of Civil Engineering Frontiers, vol. 4, no. 1, pp. 19–26, 2023.
- A. Abubakar, S. Duna, and M. Abbagana, "Performance of concrete containing metakaolin and ground scoria as partial replacement of cement," Proceedings of NBRRI International Conference, 2018.
- D. T. Woldesenbet, J. J. Mohammed, S. D. Negedu, J. Henriques, E. A. Bekele, "Experimental investigation on partial cement replacement with binary blended bagasse ash and calcined dolomite for enhanced C-25 grade concrete performance," Sci Rep., vol. 15, no. 1, p. 22844, 2025. doi: 10.1038/s41598-025-98019-7.
- J. Adebola, C. Ikumapayi, and C. Arum, "Effectiveness of Rice Husk and Sugarcane Bagasse Ashes Blended Cement in Improving Properties of Concrete," Journal of Materials Science and Chemical Engineering, vol. 11, pp. 1-19, 2023.
- F. De'nan, M. J. Megat Azmi, S. Nyandau, and N. Hashim, "The influence of palm oil fuel ash and metakaolin on the strength of concrete and crack resistance of reinforced concrete beam: a review," World Journal of Engineering, vol. 20, 2022. doi: 10.1108/WJE-01-2022-0010.
- M. Ismail, M. J. Megat Azmi, K. S. Ariffin, R. J. Putra, M. H. Ibrahim, and Y. Yugashini, "Performance of High Strength Concrete Containing Palm Oil Fuel Ash and Metakaolin as Cement Replacement Material," Advances in Civil Engineering, 2022. doi: 10.1155/2022/6454789.
- O. Zaid, A. Jawad, M. S. Siddique, and A. Fahid, "Effect of Incorporation of Rice Husk Ash Instead of Cement on the Performance of Steel Fibers Reinforced Concrete," Frontiers in Materials, vol. 8, Article 665625, 2021. doi: 10.3389/fmats.2021.665625.
- S. S. Banu, J. Karthikeyan, and P. Jayabalan, "Effect of agro-waste on strength and durability properties of concrete," Construction and Building Materials, vol. 258, p. 120322, 2020.
- S. I. Irico, L. De Meyst, D. Qvaeschning, M. C. Alonso, K. Villar, and N. De Belie, "Severe Sulfuric Acid Attack on Self-Compacting Concrete with Granulometrically Optimized Blast-Furnace Slag-Comparison of Different Test Methods," Materials (Basel), vol. 13, no. 6, p. 1431, Mar. 2020. doi: 10.3390/ma13061431.
- S. N. Chinnu, S. N. Minnu, A. Bahurudeen, and R. Senthilkumar, "Influence of palm oil fuel ash in concrete and a systematic comparison with widely accepted fly ash and slag: A step towards sustainable reuse of agro-waste ashes," Cleaner Materials, vol. 5, p. 100122, 2022. doi: 10.1016/j.clema.2022.100122.
- A. Dhanalakshmi, J. Jeyaseela, S. Karthika, and A. Leema Margret, "An experimental study on concrete with partial replacement of cement by rice husk ash and bagasse ash," E3S Web of Conferences, vol. 387, p. 03004, 2023. doi: 10.1051/e3sconf/202338703004.
- J. M. Marangu, M. Sharma, L. Scheinherrová, I. Kafodya, V. K. Mutai, E. Latif, V. I. Novelli, D. K. Ashish, and R. Maddalena, "Durability of Ternary Blended Concrete Incorporating Rice Husk Ash and Calcined Clay," Buildings, vol. 14, no. 5, p. 1201, 2024. doi: 10.3390/buildings14051201.
- B. E. Ngekpe, E. James, and F. G. Dan-Jumbo, "Durability of recycled aggregate concrete exposed to crude-oil contamination," Journal of Advanced Cement & Concrete Technology, vol. 8, no. 2, 2023.
- M. A. Akinpelu, et al., "Impact of treatment temperature of metakaolin on strength and sulfate resistance of concrete," Research on Engineering Structures and Materials, vol. 10, pp. 1261–1279, 2024.
- K. Nasrollahzadeh and M. Rostami, "Experimental Investigation on Durability of One-Part and Two-Part Alkali-Activated Slag Concretes in Sulfuric Acid Environment: Development of a Durability Index and CO2 Emission Assessment," Arabian Journal for Science and Engineering, pp. 1–28, 2025. doi: 10.1007/s13369-025-10137-6.
- L. M. Rasmusson, N. Strokirk, M. Tedengren, and M. Giese, "Acid Sulfate Soils and Their Pathways of Impact: A Swedish Case Study," Ecology and Evolution, vol. 15, no. 7, p. e71732, 2025. doi: 10.1002/ece3.71732.
- L. Guo, X. Xu, Q. Wang, X. Dong, X. Liu, and H. Lei, "Synergistic utilization of industrial waste red mud and rice husk ash for eco-friendly geopolymer preparation: enhancing strength and mitigating hazardous leaching," Environmental Science and Pollution Research, vol. 31, no. 2, pp. 2745–2758, 2024. doi: 10.1007/s11356-023-31336-4.
- K. A. A. Al-Sodani, A. A. Adewumi, M. A. Mohd Ariffin, B. A. Salami, M. O. Yusuf, M. Ibrahim, et al., "Acid resistance of alkali-activated natural pozzolan and limestone powder mortar," Sustainability, vol. 14, no. 21, p. 14451, 2022. doi: 10.3390/su142114451.
- A. A. Akindahunsi, F. Avet, and K. Scrivener, "Influence of Nigerian calcined clays as clinker substitutes," Case Studies in Construction Materials, vol. 13, p. e00443, 2020.
- A. Saha, T. M. Tonmoy, M. H. R. Sobuz, et al., "Sulphate-resisting cement concrete in saline conditions," Construction and Building Materials, vol. 420, p. 135527, 2024.
- A. Ni?, R. Alzeebaree, A. Mohammedameen, et al., "Durability of concrete under chemical environments," Iranian Journal of Science and Technology: Transactions of Civil Engineering, pp. 1–14, 2024.
- G. Gluth, C. Grengg, N. Ukrainczyk, F. Mittermayr, and M. Dietzel, "Acid resistance of alkali-activated materials: recent advances and research needs," RILEM Technical Letters, vol. 7, pp. 58–67, 2022. doi: 10.21809/rilemtechlett.2022.157.
- P. W. Ariyadasa, A. C. Manalo, W. Lokuge, V. Aravinthan, A. Gerdes, J. Kaltenbach, and B. A. Galvan, "Macro and microstructural evolution of low-calcium fly ash-based geopolymer mortar exposed to sulphuric acid corrosion," Cement and Concrete Research, vol. 178, p. 107436, 2024. doi: 10.1016/j.cemconres.2024.107436.
- J. P. Godinho, M. H. F. Medeiros, A. M. Neto, V. M. E. Lima, and D. J. De Souza, "Laboratory–field assessment of concrete exposed to biogenic sulphuric acid: Influence of SCM-based binders on long-term degradation," Construction and Building Materials, vol. 493, p. 143185, 2025. doi: 10.1016/j.conbuildmat.2025.143185.